you can not say, that the produktion "until 1935 brass/copper", until 1940 alu, than steel or mixed".
from right to left.
1. frog of 1925 with steel rivets 2. frog of 1929 copper/brass 3. leather frog 1936 alu 4.+5. A.Fischer 1937 Leather/canvas frogs in brown and withe with alu rivets. 6. frog out of 1940 with steel rivets 7.+8. Frogs from J.de Valk Adam. made 1941/42 with copper/brass.
The army issued frogs from Valk ADAM to the same time 1941-1943 were produced with steel rivtes.