Here is a guy that got killed working on a civil war 75 lb naval cannon ball a few years back ... I remember when it happened because I am into metal detecting and this story made the rounds in the MD forums. He was actually drilling into this, so obviously not like a little bump set it off, but rather sparks or friction heat - Couldn't pay me enough to mess with hardware like that, and here in Michigan, odds of finding a buried shell are pretty low.
I guess its worth remembering that an unexploded shell is still very much a lethal hazard ,,, We tend to think of "duds" as just that, a mechanical device that failed and will not work again, like a broken hammer. But it only failed because the fuse/detonator didn't properly cause it to explode, so the potential to explode always remains given the proper conditions.
http://www.foxnews.com/story/2008/05/02/virginia-man-killed-in-civil-war-cannonball-blast/